| Unlockable: | How to Unlock: |
| Cao Cao | Clear Musou Mode with 3 Wei characters |
| Cao Pi | Deafeat Cao Pi within 5 minutes on Wu side of He Fei |
| Cao Ren | Succeed in Battle Objective 2 on the Lu Bu side of Fan Castle |
| Diao Chan | Clear Musou Mode with 1 character from each Kingdom |
| Dong Zhuo | Clear Musou Mode with Lu Bu |
| Gan Ning | Clear Musou Mode with 1 Wu character |
| Guan Ping | Succeed in 2 battle objectives on the Shu side of Fan Castle and finish battle with Guan Ping alive |
| Huang Gai | Succeed in Battle Objective 3 on the Wu side of The Battle of Chi Bi |
| Huang Zhong | Succeed in 1 battle objective on the Wei side of Ding Jun Mountain |
| Liu Bei | Clear Musou Mode with 3 Shu characters |
| Lu Bu | Clear Musou Mode with Liu Bei, Cao Cao, and Sun Jian |
| Lu Meng | Succeed in 2 battle objectives on the Wei side of He Fei |
| Ma Chao | Succeed in 2 battle objectives on the Wei side of Han Zhong Attack Defense Battle |
| Pang Tong | Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive |
| Sun Ce | Succeed in Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi |
| Sun Jian | Clear Musou Mode with 3 Wu characters |
| Sun Quan | Succeed in Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi |
| Wei Yan | Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive |
| Xiahou Yuan | Succeed in 1 battle objective on the Shu side of Ding Jun Mountain |
| Xiao Quio | Succeed in Battle Objective 3 on the Wu side of the Battle of Shi Ting |
| Xu Chu | He Fei, Wu side, Personally kill Cao Ren and Xu Chu |
| Xu Huang | Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle |
| Yuan Shao | As Wei, complete all 3 targets and capture Wu Chao before completing the stage. |
| Yue Ying | Succeed in Battle Objective 1 on the Wei side of the Battle of Wu Zhang Plains |
| Zhang Liao | Clear Musou Mode with 1 Wei character |
| Zheng He | Succeed in 2 battle objectives on the Shu side of Han Zhong Attack Defense Battle |
| Zhou Tai | Succeed in 3 battle objectives on the Shu side of Yi Ling |
| Zhuge Liang | Clear Musou Mode with 1 Shu character |
| Unlockable: | How to Unlock: |
| 1st in Gauntlet (10 pts) | Rank 1st (Pesonal Best points) In Gauntlet. |
| 1st in Havoc (10 pts) | Rank 1st (Personal Best points) In Havoc. |
| 1st in Rampage (10 pts) | Rank 1st (Personal Best points) In Rampage. |
| 1st in Speed RUN (10 pts) | Rank 1st (Personal Best points) in Speed Run. |
| 1st in Sudden Death (10 pts) | Rank 1st (Personal Best points) in Sudden Death. |
| Musou Mode Master (50 pts) | All Musou modes cleared. |
| Scenario Captain (40 pts) | 30 or more scenarios cleared. |
| Scenario Corporal (30 pts) | 20 or More Scenarios Cleared. |
| Scenario General (50 pts) | All scenarios cleared. |
| Scenario Private (20 pts) | 10 or more scenarios cleared. |
| Target Captain (50 pts) | 100 or more Targets achieved. |
| Target Corporal (40 pts) | 70 or more Targets achieved. |
| Target General (60 pts) | All Targets achieved. |
| Target Private (30 pts) | 50 or more targets achieved. |
| The Arm of Cao Cao (10 pts) | Xiahou Yuan has been unlocked. |
| The Barbarian Lord (10 pts) | Wei Yan has been unlocked. |
| The Beautiful Dancer (30 pts) | Diao Chan has been unlocked. |
| The Courageous Lord (10 pts) | Xu Huang has been unlocked. |
| The Ferocious Warrior (10 pts) | Taishi Ci has been unlocked. |
| The Fledgling Phoenix (10 pts) | Pang Tong has been unlocked. |
| The Forthright Lord (30 pts) | Zhang Liao has been unlocked. |
| The General of Heaven (10 pts) | Zhang Jiao has been unlocked. |
| The Little Conqueror(10 pts) | Unlock Sun Ce. |
| The Lord Of Beauty (10 pts) | Zhang He has been unlocked. |
| The Loyal Warrior (10 pts) | Zhou Tai has been unlocked. |
| The Master General (10 pts) | Lu Meng has been unlocked. |
| The Patriarch of Yuan (10 pts) | Yuan Shao has been unlocked. |
| The Patriarch of Yuan (10 pts) | Yuan Shao has been unlocked. |
| The Reckless Pirate (30 pts) | Gan Ning has been unlocked. |
| The Sleeping Dragon (30 pts) | Zhuge Liang has been unlocked. |
| The Son Of Guan Yu (10 pts) | Guan Ping has been unlocked. |
| The Splendid One (10 pts) | Ma Chao has been unlocked. |
| The Tiger General (10 pts) | Huang Zhong has been unlocked. |
| The Tiger of Jiang Dong(10 pts) | Unlock Sun Jian. |
| The Veteran General (10 pts) | Huang Gai has been unlocked. |
| The Wise Lady (10 pts) | Yue Ying has been unlocked. |
