| Unlockable: | How to Unlock: |
| Aaroniero and Smart Espada | Beat Tag Master #13 |
| Adult Nel | Get 50000 points in Tag Master |
| Aizen | Beat Tag Master #18 |
| Bankai Ichigo's Inner Hollow | Beat Tag Master #11 |
| Chad w/ Devil's Left Arm | Beat Tag Master #7 |
| Cirruci Thunderwitch | Beat Tag Master#10 |
| Diamond Dust Rebeliion Guy | Beat Tag Master #17 |
| Espada #5 | Beat Tag Master #14 |
| Hollow Ichigo | Defeat Ichigo and Hollow Ichigo in Tag Master |
| Kuchiki Byakuya (Bankai) | Defeat him and Rukia in Tag Master Mode |
| Kuchiki Rukia (Shinigami form) | Defeat her and Byakuya in Tag Master Mode |
| Madarame Ikkaku | Defeat Ikkaku/Kempachi on Tag Master Mode |
| Pantera Grimmjow | Beat Story Mode |
| Seele Schneider Ishida | Beat Tag Master #8 |
| Senna | Beat Tag Master #16 |
| Shinji (Mask Form) | Defeat him and Hiyori in Tag Master Mode |
| Unlockable: | How to Unlock: |
| Movie 1 | Obtain 10000 Tag pts with at least one Human character in the team |
| Movie 10 | Obtain 25000 Tag pts a second time with a DIFFERENT team of one Shinigami character and one Human character |
| Movie 2 | Obtain 10000 Tag pts a second time with at least one Human character in a DIFFERENT team |
| Movie 3 | Obtain 10000 Tag pts with at least one Hhinigami character in the team |
| Movie 4 | Obtain 10000 Tag pts a second time with at least one Shinigami character in a DIFFERENT team |
| Movie 5 | Obtain 10000 Tag pts with at least one Arrancar character in the team |
| Movie 6 | Obtain 10000 Tag pts a second time with at least one Arrancar character in a DIFFERENT team |
| Movie 7 | Obtain 10000 Tag pts with at least one Vizard character in the team |
| Movie 8 | Obtain 10000 Tag pts a second time with at least one Vizard character in a DIFFERENT team |
| Movie 9 | Obtain 25000 Tag pts with a team of one Shinigami character and one Human character |
